基本信息
姓 名：邱盟峯
邮 箱：ifemfchiou@fjnu.edu.cn
职 称：副教授
学历
天主教辅仁大学化学系 博士(2014.1)
天主教辅仁大学化学系 学士(2006.6)
中国科学院海西研究院福建物质结构研究所 博士后 (2017.11 – 2022.03)
台湾交通大学应用化学所 博士后研究员(2015.09 – 2017.07)
台湾海岸巡防署南部地区巡防局 义务役少尉(2014.08 – 2015.07 服役)
台湾中研院原子分子科学研究所 博士后研究员(2014.03 – 2014.07)
获得资助中国科学院台湾青年人才计划 (2020)
海峡博士后交流资助计划 (2017)
学术领域
物理化学、计算化学、有机化学、金属催化及亲核剂催化反应
研究专长 Gaussian, VASP, fortran, Perl, Shell Script
个人简介
2014 年 1 月于天主教辅仁大学毕业取得化学博士学位，主修为物理化学及计算化学。研究所学习期间以第一名成绩取得博士班全额奖学金。研究所主要研究为以理论计算方式探讨阴离子水合团簇中的分子结构以解释光谱现象。期间因研究需要，除了计算化学必要软件 Gaussian, VASP 以外，并学习多种程序设计，熟习fortran, Perl, Shell Script。2014 年 7 月进入台湾海巡署服役一年，服役期间官衔少尉，修习法律课程并取得义务役司法警察资格。2015 年役毕后从事博士后研究工作，开始物理有机化学研究，主要以分子模拟解释各种推测中间体及过渡态，探讨反应成因及各种反应机制。2017 年取得海峡博士后交流资助计划进入福建物质结构研究所鲍红丽课题组从事博士后，2020年获得中国科学院台湾青年人才。2022 年物构所博士后出站评优，当前符合福建省高层次人才认定 c 类人才。
研究兴趣
1.以理论计算方式探讨阴离子水合团簇中之分子结构，并且由模拟分子动力学过程，藉以了解水分子的排列方式对电荷转移过程的影响。此外，藉由数值分析方法，分析团簇之水分子结构变化涉及之团簇偶极矩、游离能、电子平均分布半径变化等相关问题，进一步解释光谱现象。
2.藉由分子模拟解释各种推测之中间体及过渡态之反应性，诸如吸热、放热反应，反应能障等性质。并以电荷分布、分子轨域成分之分析进一步探讨反应成因以了解金属催化及亲核剂催化反应之各种反应机制。
学术成果
1.Li, T.; Chiou, M.-F.;(共同一作) Li, Y.; Ye, C.; Su, M.; Xue, M.; Yuan, X.; Wang, C.; Wan, W.-M.;Li, D.; Bao, H. Synthesis of Unsymmetrically Tetrasubstituted Pyrroles and Studies of AIEE in Pyrrolo[1,2-a]pyrimidine Derivatives. Chem. Sci. 2022.
2.Nie, Z.;Chiou, M.-F.;†(共同一作) Cui, J.; Qu, Y.; Zhu, X.; Jian, W.; Xiong, H.; Li, Y.; Bao, H.Copper-Catalyzed RadicalEnantioselective Carbo-Esterification of Styrenes Enabled by a Perfluoroalkylated-PyBox Ligand. Angew. Chem. Int. Ed. 2022, revise submission.
3.Ge, L.;Zhou, H.;§ Chiou, M.-F.;§(共同一作) Jiang, H.; Jian, W.; Ye, C.; Li, X.; Zhu, X.; Xiong, H.; Li, Y.; Song, L.; Zhang, X.; Bao, H. Iron-Catalysed AsymmetricCarboazidation of Styrenes. Nat. Catal. 2021, 4, 28-35.
4..Zeng, Y.;§ Chiou, M.-F.;§(共同一作) Zhu, X.; Cao, J.; Lv, D.; Jian, W.; Li, Y.; Zhang, X.; Bao, H. Copper-Catalyzed Enantioselective Radical 1,4-Difunctionalization of1,3-Enynes. J. Am. Chem. Soc. 2020, 142, 18014-18021.
5.Chiou, M.-F.; Xiong, H.; Li, Y.; Bao, H.*; Zhang, X.* Revealing the Iron-Catalyzed β-Methyl Scission of tert-Butoxyl Radicals via the Mechanistic Studies of Carboazidation of Alkenes Molecules 2020, 25, 1224.
6..Jiao, Y.;§ Chiou, M.-F.;§(共同一作) Li, Y.; Bao, H.* Copper-Catalyzed Radical Acyl-Cyanation of Alkenes with Mechanistic Studies on the tert-Butoxy Radical. ACS Catal. 2019, 9, 5191-5197.
7.Zhu, X.;§ Deng, W.;§ Chiou, M.-F.;§(共同一作) Ye, C.; Jian, W.; Zeng, Y.; Jiao, Y.; Ge, L.; Li, Y.; Zhang, X.*; Bao, H.* Copper-Catalyzed Radical 1,4-Difunctionalization of 1,3-Enynes with Alkyl Diacyl Peroxides and N-Fluorobenzenesulfonimide. J. Am. Chem. Soc. 2019, 141, 548-559.
8.Chiou, M.-F.; Jayakumar, J.; Cheng, C.-H.; Chuang, S.-C.* Impact of the Valence Charge of Transition Metals on the Cobalt- and Rhodium-Catalyzed Synthesis of Indenamines, Indenols, and Isoquinolinium Salts: A Catalytic Cycle Involving MIII/MV [M = Co, Rh] for [4 + 2] Annulation. J. Org Chem. 2018, 83, 7814-7824.
9.Chiou, M.-F.; Sheu, W.-S.* Charge-transfer-to-solvent absorption spectra of I−(H2O)3–5 at a finite temperature via simulation. Int. J. Quantum Chem. 2017, 117, e25404.
10.Sheu, W.-S.;* Chiou, M.-F. Effects of Iodine on the Relaxation Dynamics of a Photoexcited I-(H2O)4 Cluster. J. Phys. Chem. A 2013, 7, 13946-13953.
11.Chiou, M.-F.; Sheu, W.-S.* Exploring Water Binding Motifs to an Excess Electron via X2-(H2O) X= O, F. J. Phys. Chem. A 2012, 116, 7694-7702.
12.heu, W.-S.;* Chiou, M.-F. Potential Energy Surface of O2-(H2O) and Factors Controlling Water-to-O2- Binding Motifs. J. Phys. Chem. A 2011, 115, 99-104.
13.Ma, X.; Chiou, M.-F.; Ge, L.; Li, X.; Li, Y.; Wu, L.; Bao, H. Iron phthalocyanine-catalyzed radical phosphinoylazidation of alkenes: A facile synthesis of beta-azido-phosphine oxide with a fast azido transfer step. Chin. J. Catal. 2021, 42, 1634-1640.
14.Ye, C.; Jiao, Y.; Chiou, M.-F.; Li, Y.; Bao, H. Direct synthesis of pentasubstituted pyrroles and hexasubstituted pyrrolines from propargyl sulfonylamides and allenamides. Chem. Sci. 2021, 12, 9162-9167.
15.Cao, J.; Lv, D.; Yu, F.; Chiou, M.-F.; Li, Y.; Bao, H. Regioselective Three-Component Synthesis of Vicinal Diamines via 1,2-Diamination of Styrenes. Org. Lett. 2021, 23, 3184-3189.
16.Su, M.; Zhu, N.; Chiou, M.-F.; Bao, H. Synthesis of Amidine Derivatives by Intermolecular Radical Addition to Nitrile Groups of AIBN Derivatives. Synlett 2021, 32, 395-400.
17.Ge, L.; Chiou, M.-F.; Li, Y.; Bao, H. Radical azidation as a means of constructing C(sp3)-N3 bonds.Green Synth. Catal. 2020, 1, 86-120.
18.Zhang, Q.; Muhammad, M. T.; Chiou, M.-F.; Jiao, Y.; Bao, H.; Li, Y. 1,4-Fluoroamination of 1,3-Enynes en Route to Fluorinated Allenes. Org. Lett. 2020, 22, 5261-5265.
19.Taj Muhammad, M.; Jiao, Y.; Ye, C.; Chiou, M.-F.; Israr, M.; Zhu, X.; Li, Y.; Wen, Z.; Studer, A.; Bao, H.* Synthesis of difluoromethylated allenes through trifunctionalization of 1,3-enynes Nat.Commun. 2020, 11, 416.
20.Zhu, N.; Chiou, M.-F.; Xiong, H.; Su, M.; Su, M.; Li, Y.; Wan, W.-M.*; Bao, H.* The Introduction of the Radical Cascade Reaction into Polymer Chemistry: A One-Step Strategy for Synchronized Polymerization and Modification iScience 2020, 23, 100902.
21.Xiong, H.; Ramkumar, N.; Chiou, M.-F.; Jian, W.; Li, Y.; Su, J.-H.; Zhang, X.*; Bao, H.* Iron-Catalyzed Carboazidation of Alkenes and Alkynes. Nat. Commun. 2019, 10, 122.
22.Chuang, S.-C.; Sung, S.-P.; Deng, J.-C.; Chiou, M.-F.; Hsu, D.-S. Multicomponent reactions of phosphines, enynedioates and benzylidene malononitriles generated highly substituted cyclopentenes through an unexpected phosphinealpha-addition-delta-evolvement of an anion pathway. Org. Biomol. Chem. 2016, 14, 2306-2317.
