基本信息
姓 名：石乃恩
学 科：分子纳米科学与技术、信息材料学、柔性电子学、能源化学
职 称：教授
联系地址：福建省福州市闽侯县上街镇福建师范大学旗山校区
邮 箱：ifeneshi@fjnu.edu.cn
个人简历
2022.03-至今 福建师范大学 海峡柔性电子(未来科技)研究院 教授/博士生导师
2017.07-2022.03 南京邮电大学 材料科学与工程学院/信息材料与纳米技术研究院 教授/博士生导师
2012.09-2013.03 南洋理工大学 材料科学与工程系访问学者
2010.07-2017.06 南京邮电大学 材料科学与工程学院/信息材料与纳米技术研究院 副研究员、副教授
2007.06-2010.07 南京邮电大学 材料科学与工程学院/信息材料与纳米技术研究院 讲师
2002.09-2007.06 南京大学化学化工学院配位化学国家重点实验室 无机化学专业 理学博士
1998.09-2002.06 南京理工大学化学化工学院 精细化工专业 工学学士
研究方向
纳米结构功能材料、纳米配位聚合物材料、有机光电功能材料及复合柔性电子材料的设计制备与器件应用。
主要包括:
1.纳米结构材料的设计合成，与大面积薄膜溶液加工
2.纳米金属有机框架及其电荷与能量存储器件
3.光电功能复合材料与便携式荧光传感器
研究及教学工作
课题组主要从事金属有机配位聚合物与有机纳米结构材料设计制备，性质及器件应用方面的研究。①开辟了纳米金属有机配位聚合物可控制备新途径，提出了助剂对二维金属有机配位聚合物设计剪裁的结构选择性，系统探讨了系列纳米材料的电荷存储、储能和分子传感性能的结构效应；②提出了金属有机框架高质量二维超薄无卷曲纳米片合成策略，并实现了金属有机框架基高性能、多功能晶体管分子级杂化电存储器；③创新性地合成了贯通式分级孔配位聚合物低维及其衍生功能纳米结构，系统研究了其构效关系，另通过基质聚合物和微结构设计等开发了系列爆炸物荧光传感器，大大提升了检测的灵敏度和选择性。
迄今在Advanced Functional Materials, Journal of Materials Chemistry A, Chemical Communications, Small, Crystal Growth & Design, ACS Nano, Organic Electronics等期刊上发表论文60余篇，授权国家发明专利十余项，为Chemical Communications, Inorganic Chemistry, Journal of Materials Chemistry C, Journal of Hazardous Materials, Talanta, European Journal of Inorganic Chemistry等国际期刊特约审稿人；江苏省高校“青蓝工程”优秀青年骨干教师，主持7项国家自然科学基金项目与省地各级项目，参与国家自然科学基金重大、重点或面上项目等6项，入选江苏高校优秀科技创新团队(2013)，江苏省六大人才高峰创新人才团队(2016)，以及南京邮电大学135人才计划创新团队(2013)。教学方面，曾主讲《仪器分析》、《物理化学实验》、《神奇的材料》、《纳米材料化学》等本科及研究生课程，并撰写多篇教学改革论文，指导学生获“江苏省大学生化学化工实验竞赛”二等奖。
奖励荣誉
1. 2007年度南京大学优秀研究生
2. 2012年指导学生获江苏省大学生化学化工实验物理化学实验省级二等奖
3. 2015年南京邮电大学“鼎新学者”获得者
4. 2017年江苏省“青蓝工程”优秀青年骨干教师培养对象
5. 2019年优秀毕业设计指导教师
6. 2016年“六大人才高峰”创新人才团队及江苏省六大人才高峰高层次人才培养人选
7. 2021年中国民主促进会江苏省直属工作委员会先进个人
代表性论文/著作
1. N. E. Shi, H. Dong, G. Yin, Z. Xu*, S. H. Li*, A Smart Supramolecular Hydrogel: pH-Modulated Reversibly Viscoelastic Properties, Advanced Functional Materials, 2007, 17(11), 1837–1843.
2. N. E. Shi, G. Yin, M. Han, L. Jiang, Z. Xu*, Self-assembly of Two Different Hierarchical Nanostructures on Either Side of an Organic Supramolecular Film in One Step, Chemistry - A European Journal, 2008, 14(20), 6255–6259.
3. N. E. Shi, G. Yin, M. Han, Z. Xu*, Anions Bonded on the Supramolecular Hydrogel Surface as the Growth Center of Biominerals, Colloids and Surfaces B: Biointerfaces, 2008, 66(1), 84–89.
4. N. E. Shi, G. Yin, X. W. Wei, Z. Xu*, Remarkable Hexagonal Carbon tubes Transformed from zinc Tetrapyridylporphine, Carbon, 2009, 47(2), 534–538.
5. N. E. Shi, J. J. Duan, W. Xue, L. H. Xie, W. Huang, Uncommon Horn-shaped Nanoscale Coordination Polymers Based on Trimesic Amide, International Conference on Science and Technology of Synthetic Metals, July 4th-9th, 2010 (Oral presentation)
6. N. E. Shi, L. H. Xie, H. M. Sun, J. J. Duan, G. Yin, Z. Xu, W. Huang*, Facile Synthesis of Shape and Size Tunable Porphyrinoid Coordination Polymers: From Copper Porphyrin Nanoplates to Microspindles, Chemical Communications, 2011, 47(17), 5055–5057.
7. N. E. Shi*, W. Du, X. L. Jin, Y. Zhang, M. Han, Z. Xu, L. H. Xie, W. Huang*, Surfactant Charge Mediated Shape Control of Nano/Microscaled Coordination Polymer: The Case of Tetrapyridylporphine Based Metal Complex, Crystal Growth & Design, 2014, 14(3), 1251–1257.
8. S. H. Yang, Z. Q. Lin, N. E. Shi*, L. Z. Jin, M. N. Yu, L. H. Xie*, M. D. Yi, W. Huang*, A Polyhedron Supramolecular System of Endocyclic Crystalline Organic Nanostructures: the Case of Triptycenes, CrystEngComm, 2015, 17(6), 1448–1452. (Corresponding Author)
9. W. Xue, Y. Zhang, J. J. Duan, D. Liu, Y. W. Ma, N. E. Shi*, S. F. Chen, L. H. Xie, Y. Qian, W. Huang*, A Highly Sensitive Fluorescent Sensor Based on Small Molecule Doped in Electrospun Nanofibers: Detection of Explosives as well as Color Modulation, Journal of Materials Chemistry C, 2015, 3(31), 8193–8199. (Corresponding Author)
10. N. E. Shi*, Y. Zhang, D. D. Xu, C. Y. Song, X. L. Jin, D. Liu, L. H. Xie, W. Huang*, π−System based Coordination Polymer Hollow Nanospheres for Selective Sensing of Aromatic Nitro Explosive Compounds, New Journal of Chemistry, 2015, 39(12), 9275–9280.
11. N. E. Shi*, D. D. Xu, X. H. Zhou, L. Song, L. Li, L. H. Xie, L. H. Wang, M. D. Yi, W. Huang*, Shape Uniformity Control of Metal-Organic Framework Nanodisks via Surfactant and Substrate Synergetic Scissoring Effect and Their Fluorescent Sensing Properties, CrystEngComm, 2016, 18(25), 4830–4835.
12. N. E. Shi*, C. Y. Song, J. Zhang, W. Huang*, Preparation and Optoelectronic Applications of Two-Dimensional Nanocrystals Based on Metallo-Porphyrins, Acta Physico-Chimica Sinica, 2016, 32 (10), 2447–2461.
13. Y. X. Chang†, N. E. Shi†, S. L. Zhao†, D. D. Xu, C. Y. Liu, Y. J. Tang, Z. H. Dai, Y. Q. Lan, M. Han*, J. C. Bao*, Coralloid Co2P2O7 Nanocrystals Encapsulated by thin Carbon Shells for Enhanced Electrochemical Water Oxidation, ACS Applied Materials & Interfaces, 2016, 8(34), 22534–22544.
14. Y. X. Li, S. S. Wang, Y. Yu, H. Zhang, W. Y. Wang, R. Q. Yang, L. H. Xie*, F. Liu, Z. Q. Lin, N. E. Shi, L. T. Sun, W. Huang*, SMART Design of a Bulk-Capped Supramolecular Segment for the Assembly into Organic Interdigital Lipid Bilayer-like (ILB) Nanosheets, Small, 2017, 14(6), 1703151.
15. N. E. Shi, D. Liu, X. L. Jin, W. D. Wu, J. Zhang, M. D. Yi*, L. H. Xie*, F. N. Guo, L. Yang, C. J. Ou, W. Xue, W. Huang*, Floating-gate Nanofibrous Electret Arrays for High Performance Nonvolatile Organic Transistor Memory Devices, Organic Electronics, 2017, 49, 218–225.
16. W. Wu, N. E. Shi*, J. Zhang, X. D. Wu, T. Wang, L. Yang, R. Yang, C. J. Ou, W. Xue, X. M. Feng, L. H. Xie, W. Huang*, Electrospun Fluorescent Sensors on Selective Detection of Nitro Explosive Vapors and Trace Water, Journal of Materials Chemistry A, 2018, 6(38), 18543–18550. (Corresponding Author)
17. W. Xue, J. Y. Lin, B. Liu, N. E. Shi*, M. N. Yu, W. D. Wu, W. S. Zhu, L. H. Xie*, L. H. Wang, W. Huang*, Exploring Side-Chain Length Effect on b-Phase of Polyfluorene Derivatives in Electrospinning and Their Optical Behavior, Polymer, 2018, 153, 338–343 (Corresponding Author)
18. Y. N. Lu, S. L. Zhao, R. Yang, D. D. Xu, J. Yang, Y. Lin, N. E. Shi, Z. H. Dai, J. C. Bao, M. Han*, Well-Coupled Nanohybrids Obtained by Component-Controlled Synthesis and in Situ Integration of MnxPdy Nanocrystals on Vulcan Carbon for Electrocatalytic Oxygen Reduction, ACS Applied Materials & Interfaces, 2018, 10(9), 8155–8164.
19. T. Wang, R. Yang, N. E. Shi*, J. Yang, H. Yan, J. Wang, Z. Ding, W. Huang, Q. Luo, Y. Lin*, J. Gao, M. Han*, Cu,N-codoped Carbon Nanodiscs with Biomimic Stomata-like Interconnected Hierarchical Porous Topology as Efficient Electrocatalyst for Oxygen Reduction Reaction, Small, 2019, 15(43), 1902410. (Corresponding Author)
20. W. Li, P. Zhang, H. Q. Li, X. X. Sheng, Y. Li, X. X. Xu, M. D. Yi*, N. E. Shi, W. Shi, L. H. Xie, W. Huang*, A Tricolour Photodetecting Memory Device Based on lead Sulfide Colloidal Quantum dots Floating Gate, Organic Electronics, 2019, 105111.
21. S. L. Zhao, J. Yang, M. Han*, X. M. Wang, Y. Lin, R. Yang, D. D. Xu, N. E. Shi, Q. Wang, M. J.Yang, Z. H. Dai, J. C. Bao*, Synergistically Enhanced Oxygen Reduction Electrocatalysis by Atomically Dispersed and Nano-scaled Co Species in Three-Dimensional Mesoporous Co, N-codoped Carbon Nanosheets Network, Applied Catalysis B-Environmental, 2020, 260, 118207.
22. S. L. Zhao, M. Li, M. Han*, D. D. Xu, J. Yang, Y. Lin*, N. E. Shi, Y. N. Lu, R. Yang, B. Liu, Z. H. Dai, J. C. Bao*, Defect-rich Ni3FeN Nanocrystals Anchored on N-Doped Graphene for Enhanced Electrocatalytic Oxygen Evolution, Advanced Functional Materials, 2018, 18(28), 1706018.
23. Y. Yu, Q. H. Ma, H. F. Ling*, W. Li, R. L. Ju, L. Y. Bian, N. E. Shi, Y. Qian, M. D. Yi, L. H. Xie*, W. Huang*, Small-molecule-based Organic Field-Effect Transistor for Nonvolatile Memory and Artificial Synapse, Advanced Functional Materials, 2019, 29(50), 1904602.
24. Q. Luo, Z. Ding, H. Sun, Z. Cheng, N. E. Shi*, C. Song, M. Han, D. Q. Gu, M. D. Yi, Y. J. Sun, L. H. Xie, W. Huang*, A Small Molecular with a Big Scissoring Effect: Sodium Dodecyl Sulfate Working on Two-Dimensional Metal Organic Frameworks, CrystEngComm, 2021, 23(6), 1360-1365. (Corresponding Author)
25. W. Xue, M. Xu, M. N. Yu, H. M. Sun, J. Y. Lin*, R. C. Jiang, L. H. Xie, N. E. Shi*, W. Huang*, Electrospun Supramolecular Hybrid Microfibers from Conjugated Polymers: Color Transformation and Conductivity Evolution, Chinese Journal of Polymer Science, 2021, 39, 824–830. (Corresponding Author)
26. Z. Ding, Z. Cheng, N. E. Shi*, Z. X. Guo, Y. B. Ren, M. Han, M. Y. Chen, L. H. Xie, W. Huang*, Dual-Electroactive Metal–Organic Framework Nanosheets as Negative Electrode Materials for Supercapacitors, Chemical Engineering Journal, 2022, accepted. (Corresponding Author)
27. N. E. Shi*, J. Zhang, Z. Ding, H. Jiang, Y. Yan, D. Q. Gu, W. Li, M. D. Yi*, F. Z. Huang, S. F. Chen, L. H. Xie, Y. B. Ren, Y. Li, W. Huang*, Ultrathin Metal–Organic Framework Nanosheets as Nano-Floating-Gate for High Performance Transistor Memory Device, Advanced Functional Materials, 2021, 2110784.
专利
1. 一种聚苯乙烯-卟啉衍生物纳米垂直阵列薄膜及其制备方法与应用；石乃恩，顾大庆，仪明东，丁震，黄维，于洋；ZL 202010400448.8，2021.09.28
2. 一种金属有机框架纳米片及其制备方法；石乃恩、闫鸿钰、顾大庆、罗青、丁震、黄维；ZL 201910763107.4，2021.11.09
3. 检测TNT的荧光纳米纤维薄膜及其制备方法与应用；石乃恩，吴万丹，黄维，汪联辉，薛伟；ZL 201810669250.2，2020.06.19
4. 一种系列PdxSny合金纳米晶及制备方法及应用；石乃恩，杨瑞，王涛，韩敏；ZL 201811099250.X；2021.07.13
5. 金属卟啉框架纳米晶结构的制备方法；石乃恩，王涛，闫鸿钰，王钧义；ZL 201910378154.7，2021.08.27
6. 检测潮湿环境爆炸物蒸气的多孔纳米纤维薄膜及其制备方法与应用；石乃恩，吴万丹，解令海，黄维，汪联辉；ZL 201810651143.7，2019.08.27
7. 掺杂咔唑衍生物的聚合物纳米纤维薄膜及制备方法和应用；石乃恩，薛伟，解令海，黄维，马亚威；ZL 201510465371.1，2018.06.29
8. 聚苯乙烯/卟啉衍生物复合纳米纤维及其制备方法和应用；石乃恩，刘栋，仪明东，薛伟，解令海，黄维；ZL 201610066234.5，2018.05.11
9. 一种铕基金属有机框架六棱片及其制备方法与应用；石乃恩，徐丹丹，周馨慧，宋林，黄维；ZL 201610219036.8，2018.03.06
10. 聚氟乙烯类聚合物图案化薄膜的制备方法；石乃恩，刘栋，黄维，李兴鳌；ZL 201610144311.4，2017.10.17
11. 蝶烯类有机纳米材料及制备方法；黄维，解令海，杨苏慧，林宗琼，石乃恩，仪明东；ZL 201310145424.2，2015.03.11
12. 一种纳米氧化锌与发光有机物的复合物及其制备方法；石乃恩，黄维，解令海，魏昂；ZL 200910234038.4，2013.05.08
13. 复杂螺芳基芴材料及其制备和应用方法；黄维，解令海，张龙，石乃恩；ZL 200910024456.0，2012.06.27
14. 1,8-咔唑类聚合物光电材料及其制备和应用方法；黄维，刘冉冉，解令海，石乃恩；ZL 200810234970.2，2011.08.13
